![]() The reaction occurs when oppositely charged ions in solution overcome their attraction for water and bind to each other, forming a precipitate that separates out from the solution. In a precipitation reaction, aqueous solutions of soluble salts react to give an insoluble ionic compound – the precipitate. In this reaction, sodium and silver cations exchange partners - pairing with nitrate and chloride anions, respectively - to form sodium nitrate and silver chloride. Salt metathesis is a chemical process in which the positive and negative ions of two ionic reactants exchange partners to form two new ionic products. This is an example of a salt metathesis reaction, which is also called a double displacement reaction. The molecular equation for this precipitation reaction suggests that aqueous sodium chloride reacts with aqueous silver nitrate to form aqueous sodium nitrate and solid silver chloride. Therefore, sodium nitrate is a soluble salt that remains in the solution as dissolved sodium ions and nitrate ions, while silver chloride is an insoluble salt that precipitates from the solution. ![]() Most chloride salts are water-soluble, but silver salt is an exception. According to this guide, all nitrate salts are water-soluble without exception. Referring to the solubility rules allows us to determine whether the ionic products are water-soluble or water-insoluble. Thus, sodium cations pair with nitrate anions to form sodium nitrate, and silver cations combine with chloride anions to form silver chloride. Since oppositely charged ions are attracted to each other, the cation from each reactant can pair with the anion from the other reactant to form new ionic products. When the two solutions are mixed, the resulting solution contains all four ions: the sodium and silver cations as well as the chloride and nitrate anions. Similarly, an aqueous solution of silver nitrate contains dissociated silver ions and nitrate ions. An aqueous solution of sodium chloride contains sodium ions and chloride ions in their dissociated forms. Sodium chloride and silver nitrate are water-soluble ionic compounds. The precipitate stays undissolved and can be separated from the solution by filtration. If mixing aqueous solutions of two different ionic compounds results in a chemical reaction that produces an insoluble ionic solid - called the precipitate - it is a precipitation reaction. Water molecules then surround the dissociated ions to form an aqueous solution. Water-insoluble ionic solids stay undissolved or undissociated in aqueous solutions. Water-soluble ionic solids dissolve by breaking up - or dissociating - into ions. Precipitation reactions are also useful to extract elements, like magnesium, from seawater.Ionic solids may be water-soluble or water-insoluble. For example, a barium nitrate solution will react with sulfate ions to form a solid barium sulfate precipitate, indicating that it is expected that sulfate ions are present. Precipitate development is valuable in the detection of the type of cation in a salt. Subsequently, the precipitate may easily be separated by filtration/decanting or centrifugation. Antisolvent is added – This radically drops the solubility of the desired product.Using a supersaturated solution – Without sufficient force of gravity (settling) to bring the solid particles together, the precipitate remains in suspension.The chemical that leads the solid to form is called the precipitant. Temperature of a solution is lowered – The lower temperature reduces the solubility of a salt, resulting in its precipitation as a solid.Two soluble salts react in solution to form one or more insoluble products.Powders derived from precipitation are known as flowers. The precipitate-free liquid remaining above the solid is called the supernate or supernatant. Precipitate is referred to as a pellet after sedimentation when using a centrifuge to press it into a compact mass. When the reaction occurs in a liquid solution, the solid formed is called the precipitate. Precipitation is the creation of a solid in a solution or inside another solid during a chemical reaction or by diffusion in a solid.
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![]() An agreement had recently been signed with the City of Cape Town and SASSA would be servicing clients through 93 community halls in addition to the 11 offices. SASSA explained that it had not had access to community halls in Cape Town since the start of the pandemic and had been offering services to all their clients in the area though 11 SASSA offices. SRD to be reserved for those affected by lapsed TDGs only. Balance to be reserved for responses to disasters. Limited Social Relief of Distress (SRD) would be provided within budget to TDG clients who apply while they are waiting for an assessment at R500 per month per person for maximum of 2 months on approved applications for an estimated 150 000 clients: R150 million of R190 million budget available. Total for reinstatement : 16 024 of 214648 Those receiving TDG through administrator: 73 Those receiving TDG through procurator: 577 Those receiving TDG and grant in aid: 6 079 SASSA officials stated that the agency would reinstate the grants for the most vulnerable categories of temporary disability grant (TDG) clients: She was clarifying, publicly, that she would never ask the police to spray vulnerable people, people in wheelchairs and children. It was she who had the told the police to stop because she did not think that it was a good thing to do. She had dealt with the people and then, while she was in the SASSA office for a meeting and a press conference, the police had sprayed the people with water from the water cannon. ![]() She was not running away from the people. The Minister was adamant that her intention in getting into the Casspir was to use its equipment. ![]() She had only climbed into the Casspir to use its loud hailer because DSD did not have a loud hailer. The first thing that she had done in Bellville was to speak to the people in the queue at the SASSA offices and ask them to maintain social distancing. She responded to the misperception of the Minister getting into the Casspir at the Bellville offices and the suggestion that she was not in touch with the people. The Minister pointed out that the consideration of the dignity of people was central to her approach. She and her team had been visiting sites across the country, even though they feared catching the virus. The Minister explained that Department had been working with other departments because the ultimate challenge, with or without Covid-19, remained poverty, unemployment, inequality and easy to access, properly planned government services. The Committee met on a virtual platform for a briefing by the Minister of Social Development, the Department of Social Development (DSD) and the South African Social Security Agency (SASSA) on the challenges about temporary disability grants, reapplications and overcrowding at SASSA offices. Video: Portfolio Committee on Social Development, 20 January 2021 ![]() They can regulate their breathing as they watch items move slowly around the bottle. ![]() This kind of sensory bottle is a fabulous tool to use with children experiencing big emotions. ![]() You May Also Enjoy Awesome Sensory Play Environments For Kids In Ireland Slow Motion Sensory Bottles But what if we could add the sense of smell too? Why not add a few drops of your favourite scented essential oils to some dried rice and add this to your rainstick for a sensory treat? In the case of the rainstick bottle, a hearing element is added. Sensory or calm down bottles are typically a visual tool. Secure the lid and then slowly tip the rainstick from one end to the other to hear the ‘rain’ sounds inside. water bottle, cardboard tube with the ends covered, etc) with twigs and sticks, and then carefully pour in your smaller items (uncooked rice or beans, sand, seeds, pebbles, etc). Why not include a nature scavenger hunt or trail in your quest to find items for your rainsticks? Children will love hunting for twigs, cones and small stones – and you can add in bird seed and nuts for effect too, like these rainsticks from Chalk Academy.įill the cylinder (e.g. Just add your chosen objects to fill around half of your container, secure the lid and be transported by the soothing sounds. Rainstick bottles use the calming effect of the sound of rain to sooth your child’s troubles away, and can be made from a huge array of household items such as dried rice, beads or buttons. You May Also Enjoy 21 Awesome Gifts For Children With Additional Needs Rainsticks Some require a little more adult supervision than others, so we have provided ingredients and instructions to get your craft session started! We wanted to share some of our favourite DIY sensory bottles – all of which offer a unique element for discovery and exploration, which are sure to be a hit with children of all ages. You May Also Enjoy 7 Simple Sensory Box Ideas Make Your Own Sensory Bottles Or, alternatively, use it to calm down and as a meditation tool. They can explore textures, colours and contents by shaking, rolling and up-ending the bottle. The best bit is that the overall purpose of a sensory bottle is entirely open to your child to determine. They also make a great craft activity and are simple to make. A sensory bottle, calm down jar or other similar items can offer a valuable focus or distraction to a child while they calm down from an overwhelming emotional experience. One of the most effective uses for sensory bottles is as a calm-down tool. They can also help with the development of fine motor skills when children are involved in making the bottles, and language and social skills when shared. Like all sensory play, sensory bottles are a really useful tool for promoting a sense of wonder and encouraging children to use their senses to explore and discover. And the actual act of making sensory bottles or calm down jars is in itself a wonderful activity! Discover how you can make different styles of sensory bottles at home with our round-up below.ĭon’t miss our best content straight to your inbox! Sign up now and get our FREE newsletters packed with fun ideas and things to do with the kids, family-friendly recipes, expert advice, parenting tips and great competitions. When emotions become too much, having something to help your child calm down is a great idea. ![]() I would lose track of deadlines left and right and they would creep up on me at the last minute. –Sean Biehle, MedData Stressful, impossible, difficult, overwhelming. Honestly, it has way too much stuff going on. –Wanda Whipkey, World Elite Asana did not have very good analytics and, despite being designed by a few former Facebook employees, was not very user-friendly. Every team member was working alone during catch up meetings that became very clear. Of course, not having any idea what may be coming next. –Amber Hinds, Road Warrior Creative Before basecamp it felt like sitting in a wind tunnel with projects, emails, and questions flying at you. –Christy Benny, NBT Bank We had a hard time keeping clients on track with their to-do items - projects frequently fell behind both because of missed communication but also because there wasn’t anything reminding clients of their responsibilities and the tasks they had to complete. It was difficult to understand and flow when conducting or even being part of a project. –Jarrad Markel, Mastermind Media and Consulting Group Inundated with emails - easy to lose track as people would contact via various mediums and conversations can get lost in the back and fourth –G Davies, The Breakfast Club My company used Trello before a department switched over to Basecamp. Tracking down communications and documenting tasks was nearly impossible. ![]() –Adam Faust, 5+8 There were a lot of holes in our communication which led to projects being lost in the shuffle and/or not done on time. I couldn’t get a true handle on anything. –James Hart, For the City Network I felt like I was floating in space. ![]() Once we tried to implement a project management system (SCRUM) on top of the tools my team was about ready to slam their monitors against the post-it note covered whiteboard. WAY too many tools that led to more balls getting dropped that work actually getting done. –Aleksandra Sasin, Navigatus It was a disorganized mess with a splash of chaotic disaster. I was forever worried things were slipping and not getting done. I was constantly making new lists, losing old ones, crossing off items and adding new ones. –Andy Croll, CoverageBook I felt disorganized. Slack made both me and my laptop cry with how it took over my working life. ![]() ![]() Swedish colonists occupied some of this territory in 1638, establishing Fort Christina (present Wilmington) on the western shore of Delaware Bay. Maryland's northern boundary under the 1632 charter ran through the present city of Philadelphia, including a substantial swath of territory later included in Pennsylvania and Delaware and leading to a long-lived boundary dispute. In practice, Maryland benefited from the experience of Virginia, avoiding some pitfalls, and generally following patterns already established in the Old Dominion. The Calvert family, as Proprietors of Maryland, granted land to whom they pleased, drawing an income from their generosity in annual quitrents, and filled the offices of government with their relatives. In theory, and to some extent in practice, Maryland was a family affair. The southern bank of the Potomac was the boundary between Baltimore’s domain and Virginia as far as Chesapeake Bay the line crossed the bay to bisect the Eastern Shore between Watkins Point and the Atlantic. The northern boundary ran westward from Delaware Bay along the fortieth parallel to the "first fountain" of the Potomac River. This tract of some 12 million acres included a considerable part of the grant made to the Virginia Company of London in 1609. On JKing Charles I granted land on the upper reaches of Chesapeake Bay to his son Cecilius Calvert, 2nd Lord Baltimore, as sole proprietor. Sir George Calvert, 1st Lord Baltimore in the Irish Peerage, died before completing negotiations. Maryland was intended as a refuge for English Catholics, but Leonard Calvert, the first governor, had explicit instructions to "suffer no scandal nor offence to be given to any of the Protestants." To maintain this balance, Maryland authorities embraced a broad religious tolerance from the beginning. ![]() They then sailed up Chesapeake Bay to the mouth of the Potomac River and began a search for an appropriate spot for their settlement. In 1634 two ships, the Ark and the Dove, arrived in Virginia from England with settlers for a new colony to be called Maryland. The Maryland Colony and Religious Freedom In the seventeenth century Ulster Scots chose the Chesapeake colonies, the goal for most emigrants from the British Isles, and most of them migrated to Maryland. history, specializing in Colonial America. in American history from Georgetown University he taught U.S. He is affiliated with the Center for Scotch-Irish Studies and the Department of History at the University of Florida. Richard MacMaster is co-editor of The Journal of Scotch-Irish Studies. ![]() In these cases, please wait 48 hours for your ability to be reinstated. For example, if you have reached out to our team to reset your two-factor authentication, or you have changed your password, we will temporarily disable your ability to withdraw. Occasionally, we may need to lock your account if you have made recent changes to it. Recent Account Changes (Including Password Changes) ![]() Please open a chat session with Customer Support, and we'll ask for the necessary documentation. Account VerificationĪnother reason we may lock your withdrawal function is that our firm needs to finish verifying your identity. Please contact us thereafter, and our team will be happy to help you with the next steps. If you'd like to review that information, click here. Note : There are deposit holds in place to help prevent accounts from going negative. If you want to review how to make a deposit, or different ways of depositing, you can visit our USD Transfers support page here. To regain access to your account, we'll need you to settle the outstanding balance by making a new deposit. To Restore Access (From a Negative Account Balance): You can see the status of your deposit by viewing your deposit and withdrawal history.
The sensing leg for the gauge (the tan wire) is connected to the sender. What do you mean by shorted to ground? I'm slightly electrically dumb. The truck is running and operating, I'm in the process of cleaning up the harness and I'm just lacking water temp and oil pressure. A tan wire to the brake pressure warning switch on the proportioning valveĪ nice clear wiring diagram of the 1984 C/K engine compartment: The purple lead from the ignition switch to the solenoid S terminalĤ. The two red branch lines that also go to the B terminalģ. Main (black) cable from battery positive to the solenoid B terminalĢ. Other critical wiring in the engine compartment:ġ. The blues enter separately and are spliced inside the plug casing.Ħ - The small red and brown to the alternatorĨ & 11 - Coil primary and pulsed signal for a tachometer Note- the following leads are normally grouped together in a single harness connector :ģ,4 & 5 - To the oil pressure switch. The white wire to the TACH terminal of the distributor (if you have a tachometer) The main ground cable from the battery negative to the alternator bracketġ1. The flat braided ground strap (cab firewall to RH cylinder head)ġ0. The pink to the BATT terminal on the distributor (coil primary feed)ĩ. The big red to the alternator (battery charging and system supply)Ĩ. The two small wires (red & brown) to the alternator (excitation & voltage indication)ħ. The light blue from the oil pressure switch over to the choke heaterĦ. The dark blue out of the oil pressure switch to the choke warning lightĥ. The pink/white power feed to the oil pressure switchĤ. ![]() The tan wire to the oil pressure sender (yours is probably shorted to ground)ģ. The green wire to the coolant temp senderĢ. These are the functions/colors of the wires required to run/monitor/start/charge your engine:ġ. This is a good chance to strip the engine wiring down to the essentials. Whether you’re a beginner or an experienced streamer, the Naivaunsin Video Capture Card Streaming is a valuable tool to have. Although there may be occasional issues with video signal and audio, the overall performance and affordability make it a great choice for those looking to enhance their streaming capabilities. The built-in audio input/output ports and 3.5mm microphone make it convenient for capturing and streaming audio. With its easy-to-use design, multiple compatibility, and high-quality recording capabilities, it provides a seamless and immersive experience for gamers and content creators. The Naivaunsin Video Capture Card Streaming is a reliable and efficient device for capturing and streaming gameplay. It has a durable aluminum alloy shell for heat dissipation and comes with 24 hours customer service for any assistance needed. ![]() The Capture Card Nintendo Switch offers HD capture with smooth performance and no delay, making it a great choice for gamers and content creators. With its compact size and portable design, it is ideal for live broadcasts, video recording, and conference rooms. Additionally, the capture card has a built-in 3.5mm microphone and audio input/output ports, allowing for easy voice streaming and recording. It comes equipped with a USB3.0 cable and an HDMI cable for added convenience. The capture card features a plug-and-play design with no need for driver installation, making it easy to use. It is compatible with PS5, PS4, PC, OBS, and Xbox, making it suitable for a wide range of systems and software. The Capture Card Nintendo Switch is a high-quality HDMI game capture card that supports 4K input and provides video capture for streaming and recording in 1080P 60FPS. If you're serious about elevating your content and delivering professional-grade videos, this capture card is a must-have investment that will elevate your creative journey to new heights! Whether I'm live-streaming my gaming sessions, creating YouTube videos, or conducting online tutorials, the Audio Video Capture Card with Microphone has become an essential tool in my content creation arsenal. ![]() The setup is simple and user-friendly, making it ideal for both beginners and seasoned creators. The inclusion of a microphone input is an added bonus, enabling me to record crystal-clear audio along with my videos. Whether I'm using a gaming console, DSLR camera, or even my smartphone, the capture card effortlessly connects and delivers top-notch performance. What sets this capture card apart is its seamless integration with various devices. The 4K HDMI loop-out feature ensures I can record high-resolution videos at 1080p 60fps, guaranteeing stunning visuals that captivate my audience. The Audio Video Capture Card with Microphone is a game-changer for content creators like me! This little device has revolutionized the way I capture and share my content, providing me with endless possibilities and exceptional quality. This product has a rating of A.* What does this rating mean? ![]() Third-Generation iPoděy this point, everyone has heard of the iPod but not everyone owned one. In doing so, the iPod’s packaging begins to distance the iPod from other Apple products. In a change from earlier boxes, Apple placed a plastic insert inside the box, though maintained the gray cardboard cover for the accessories slot.įriday AnalysisĚpple welcomes Windows users into the fold. The sans-serif iPod name appears on this box’s inner doors, illustrating that the iPod was very definitely a separate brand from other Apple products. The inner box’s gray is more modern-muted rather than metallic. On my Windows 20GB box, an iPod adorned with case and remote control takes up one side of the box, indicating that this was more than your older brother’s iPod. The full-face and side views remain but are slightly larger than on past boxes (perhaps to reflect the greater capacity of the high-end models). And the box identified what kind of computer the iPod was designed for (Windows or Macintosh). ![]() The name on the front of the box was simple and anything but overwhelming-the name appeared in white letters against a gray background. The iPod had now clearly become a known quantity. ![]() Second-Generation iPod With the second generation of iPods, Apple took the device cross-platform and bundled accessories. The inner box is identical to the original iPod’s box-even maintaining the serif font from the original.įriday Analysis The iPod’s doing well, but still building momentum. To again underscore how sleek the iPod was, one side of the outer box carries a side-view of the player. For the first time, the name appeared in its sans-serif font form-a form that remains today. Rather than plaster one side of the box with the word “iPod,” Apple placed the name below the left corner of the iPod full-face shot on the outside of the box. And the inner box is the same silver as the original, again parroting the Mac’s brushed metal appearance.īut the box also reflects that the iPod was becoming its own brand, separate from the Macintosh. ![]() The box carries the images of iconic musicians (Billie Holiday, for example) portrayed similarly to the figures presented in Apple’s Think Different ad campaign. And to hint at just how sleek the iPod is (or was at the time), one side of the box features an iPod at a 45 degree angle.ġ0GB iPod The 10GB iPod that followed on the heels of the original also hints that it was designed for Mac users. The full face shot includes a pair of earbuds to let buyers know that it’s a device for playing music. The box was also designed to communicate the iPod’s purpose and to distinguish it from other music players. The inner box and back “features” label on one side of the outer box are silver, reflecting Mac OS X’s brushed metal theme. The outer box screams iPod in bold black letters using the default Apple font that all Mac users are familiar with. Original 5GB iPod This iPod was designed for Macintosh only and the box reflects a design that would be familiar to Mac users. It also speaks volumes (okay, maybe short stories) about how Apple perceives its player. I’d like to posit that the packaging that surrounds the iPod serves a purpose greater than encasing Apple’s music player in a pretty wrapper. In this Friday frame of mind, that shelf and the new packaging that accompanies the latest iPod releases sparked an idea. ![]() Add a few LED lights to complete the effect. If you want love Iron Man, though want something a bit less involved, go with this arc reactor. In the designer’s own words, “It looks great, but it is NOT comfortable.” It’s a good thing that when you’re not wearing it, the costume makes great display pieces. It’s an impressive build!Īs cool as it looks, it’s an involved build and may be best tackled by experienced printers. It is based on the design of Tony Stark’s MK6 armor from the 2008 movie. This Iron Man suit 3D printed cosplay armor is a popular choice among the fans of this comic book hero. Projects like these can see life beyond Halloween with cosplay events or comic conventions. If you have the time and are up for a more challenging project, you can go beyond masks and accessories and print a full costume. Wizard Wandĭeath whistles sound horrifying at any time, and can add some terror to your Halloween. If you’re looking for a particular show, try these from Voyager, Discovery, or Picard. This Next Generation badge has a space for a magnet to easily attach it to a shirt. Turn any primary colored shirt into a Starfleet uniform (good enough for Halloween, anyway) with these Star Trek Badges. (You’ll have to make your own lightsaber sounds, but that’s part of the fun!) Choose the Dark Side with Darth Vader’s blade or the Light Side with Luke’s lightsaber. ![]() ![]() Print the hilt in one color and the blade in another color. We made this simple one that prints in place and has a collapsible telescoping blade. You can go simple or screen accurate if you prefer. There are many (like, many many) 3D models available. 3D Printed Star Wars LightsabersĪ simple lightsaber prop can be the centerpiece of a jedi or sith costume. A few of these props may be worth building a costume around. You may be able to find a printable model to finish your costume. Maybe you need that one accessory to pull your look together, or a prop you can’t find for sale. Related Post – New to 3D printing or not quite sure where to start? Check out our Elementary Guide to 3D printing. Make a magical appearance with these glasses and attached lightning bolt scar. Here’s another simple and minimal effort costume. |
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